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A.
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- Principles :
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Natural
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temperature (T)
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Synthetic
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Minerals
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Hydraulic minerals
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time (t) pressure (p)
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An analogy to transformation of sedimentary into metamorphic
rocks! Difference in T, t, p !
- Steps :
| Disintegration of original
structure |
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1.
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Mechanical crushing and grinding
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2.
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Thermal decomposition
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3.
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Structural rearrangement
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4.
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Melting
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| Formation of new structures |
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1.
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Occurrence of intermediate products
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2.
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Genesis and growth of final clinker minerals
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3.
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Crystallization of liquid phase
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- Clinker Formation : 
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Temperature (oC
)
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Process
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Reaction
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100
150 - 300
600
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drying
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free water evaporates water of crystallization driven
out OH-molecules driven out
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------600--------------------------------------------------------
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900 ~ 1000
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calcining
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CO2 driven out
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CaCO3
CaO + CO2
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> 800
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first reaction of the components
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------1100-------------------------------------------------------
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1250
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sintering
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Formation of a liquid phase Al2O3,
Fe2O3 and their compounds
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max. 1450
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clinkering
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Formation of clinker minerals (reaction of CaO with
SiO2, Al2O3 and Fe2O3)
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------1400-------------------------------------------------------
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1260 ~ 1200
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cooling
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crystallization of the clinker phases : C2S,
C3S, C3A and C4AF
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